A study of cis-dichlorobis(methylamine)platinum(II): Crystal and molecular structures of two crystal forms |
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| Institution: | 1. CNRS, UPR 8521, PROMES, Rambla de la thermodynamique, F-66100 Perpignan, France;2. INRA, UR0050, Laboratoire de Biotechnologie de l''Environnement, Av. des Etangs, F-11100 Narbonne, France;3. University of Perpignan Via Domitia, 52 Av. Paul-Alduy, F-66100 Perpignan, France;1. Institute of Radiation Problems of Azerbaijan National Academy of Sciences, AZ 1143, B.Vahabzade 9, Baku, Azerbaijan;2. Department of Nanotechnology and Radiation Material Science, National Nuclear Research Center, AZ 1073, Inshaatchilar pr. 4, Baku, Azerbaijan |
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| Abstract: | A new synthesis of cis-dichlorobis(methylamine)platinum(II) is described. It appears that during the crystallization process at least two types of crystals are formed. Form A is monoclinic with space group P2 1/n and unit cell dimensions a = 6.272, b = 15.726, c = 7.419Å, β = 99.86°, V = 721Å 3, Z = 4, R = 0.055. Form B is monoclinic, with space group P2 1/c and unit cell dimensions a = 16.078, b = 6.372, c = 21.459Å, β = 92.7°, V = 2196Å 3, Z = 12, R = 0.057. The two forms can be readily distinguished by IR spectroscopy. |
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