High-spin iron(II) complexes of ortho-functionalized paraquinones as models for quinone binding sites in reaction centres of photosynthetic bacteria |
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| Affiliation: | 1. Department of Chemistry, Faculty of Science, Bhupal Nobles''s University, Udaipur-313002, Rajasthan, India;2. Department of Analytical and Inorganic Chemistry, Faculty of Sciences, University of Concepcion, Concepcion, 4070371, Edmundo Larenas 129, Chile;3. Department of Chemistry, PAHER University, Udaipur-313003, Rajasthan, India;4. Medical Mycology and Bacteriology Research Center, Kerman University of Medical Sciences, Kerman 7616913555, Iran;5. Department of Biomedical and Pharmaceutical Sciences, University of Montana, Missoula, Montana 59812, United States |
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| Abstract: | In an attempt to mimic the iron–quinone couple of bacterial reaction center, spectral, magnetic and Mössbauer characterization of seven high-spin iron(II) complexes of the ortho-functionalized paraquinones is reported where the quinones are coordinated in their fully oxidized, monoanionic form. |
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