Thermodynamics of complexation of lanthanides by 3- and 4-hydroxybenzoic acids |
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| Institution: | 1. Anhui Key Laboratory of Advanced Building Materials, School of Materials Science and Chemical Engineering, Anhui Jianzhu University, Hefei 230601, PR China;2. CAS Key Laboratory for Mechanical Behavior and Design of Materials, University of Science and Technology of China, Hefei 230026, PR China;3. Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, PR China |
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| Abstract: | The thermodynamic parameters (log β101, ΔH101, and ΔS101) for the formation of the 1:1 complexes between lanthanide cations and 3- and 4-hydroxybenzoate anions were determined by potentiometric and calorimetric titrations in aqueous solutions of 0.10 M (NaClO4) ionic strength at 25 °C. |
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