Intermediate spin protoporhyrin(IX) iron(III) complexes |
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| Affiliation: | 1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Science, Novosibirsk, Russia;2. Novosibirsk State University, Novosibirsk, Russia;1. Shandong Key Laboratory of Microbiology, College of Plant Protection, Shandong Agricultural University, Taian, Shandong 271000, China;2. State Key Laboratory for Agrobiotechnology and Department of Microbiology, China Agricultural University, Beijing 100193, China;3. School of Biomedical Sciences, Faculty of Medicine, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China |
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| Abstract: | ‘Intermediate’ spin iron(III) has been identified, using Mössbauer spectroscopy, in materials containing protoporphyrin(IX) iron(III). These materials were all precipitated from acid pH in the presence of a variety of ligands. The implications of the results are discussed both in comparison to other known ‘intermediate’ spin porphyrins and for their relevance to haem proteins. |
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