Synthesis of some ruthenium complexes with mixed diimine ligands |
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| Affiliation: | 1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, Novosibirsk, 630090, Russia;2. Novosibirsk State University, Novosibirsk, 630090, Russia;3. Department of Chemistry and the Center for Photochemical Sciences, Bowling Green State University, Bowling Green, OH 43402, USA;1. Department of Physics, University of Sri Jayewardenepura, Gangodavila, Sri Lanka;2. Center for Advance Material Research, University of Sri Jayewardenepura, Sri Lanka;3. Department of Physics and Astronomy, Georgia State University, Atlanta, GA, United States;4. Department of Chemistry, Georgia State University, Atlanta, GA, United States;1. Department of Chemistry and Biochemistry, University of California – San Diego, 9500 Gillman Drive, La Jolla, CA 92093, United States;2. Department of Chemistry, University of California – Irvine, Irvine, CA 92697, United States;3. Kansas City University of Medicine and Biosciences, 1750 Independence Ave, Kansas City, MO 64106, United States;4. Berkeley Global Science Institute, BG6 Giauque Hall, Berkeley, CA 94720, United States;5. Department of Chemistry and Biochemistry, University of San Diego, 5998 Alcala Park, San Diego, CA 92110, United States |
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| Abstract: | The use of Ru(DMSO)4Cl2 and Ru(PY)4Cl2 (DMSO=dimethyl sulphoxide; Py=pyridine) in synthesizing mixed ligand complexes is reported. The bidentate ligands used are of the diimine type, namely, 2,2′-bipyrimidine (bpm); 3,6-di-(2-pyridyl)-1,2,4, 5-tetrazine (dpt); 2,3-bis(2-pyridyl)-5,6-dihydropyrazine (dhp); 2,3-bis(2-pyridyl)-pyrazine (dpp); 2,3-bis-(2-pyridyl)-quinoxaline (dpq); 2,3,5,6-tetrakis(2-pyridyl)-pyrazine (tpp). Characterization of the complexes has been accomplished using elemental analysis, conductivity, IR and UV-Vis spectroscopy. |
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