On the excited state disproportionation of Ru(bipy) 32+ |
| |
| Affiliation: | 1. Division of Cosmetic Science and Technology, Daegu Haany University, Gyeongsan, 38610, Republic of Korea;2. Department of Pharmacology, School of Dentistry, Kyungpook National University, Daegu, 41940, Republic of Korea;3. Department of Biochemistry, School of Medicine, Gyeongsang National University, Jinju, 52727, Republic of Korea;1. Department of Chemistry, Loyola College, Chennai 600 034, India;2. Loyola Institute of Frontier Energy, Loyola College, 600 034, India;3. Department of Chemistry, SDNB Vaishnav College for Women, Chennai 600 044, India;4. Department of Chemistry, Presidency College, Chennai 600 005, India;1. Department of Bioinformatics, Maulana Abul Kalam Azad University of Technology, WB (Formerly, West Bengal University of Technology), BF-142, Sector-I, Salt Lake, Kolkata 700064, West Bengal, India;2. Natural Science Laboratory, Division of Medecinal and Pharmaceutical Chemistry, Department of Pharmaceutical Technology, P.O. Box – 17020, Jadavpur University, 188 Raja Subodh Chandra Mullick Road, Jadavpur, Kolkata 700032, West Bengal, India |
| |
| Abstract: | The disproportionation of ( 3CT)Ru(bipy) 32+ in homogeneous solutions has been investigated by laser flash photolysis where excitations were carried out with high intensities (250>Iab> 70 MW/cc) of monochromatic light (λ excit ∼440 nm). Such a disproportionation reaction competes, at a nearly diffusion-controlled rate, with the unimolecular (radiation and radiationless) relaxation. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
