|
|||||
|
|
First syntheses and X-ray structures of a meso-alkyl-substituted corrole and its Ga(III) complex |
|
| Authors: | Simkhovich L Goldberg I Gross Z |
| Affiliation: | a Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Haifa 32000, Israel b School of Chemistry, Tel Aviv University, Tel Aviv 69978, Israel |
| Abstract: | The solvent-free condensation of heptafluorobutanal and pyrrole leads to the corresponding meso-alkyl-substituted corrole, which was metallated by gallium chloride to provide the first first-row non-transition-metal corrole. Both the ligand and the complex were characterized by X-ray crystallography. |
| Keywords: | Corroles Meso-alkyl-substituted corrole Gallium complex |
| 本文献已被 ScienceDirect PubMed 等数据库收录！ | |