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Comparative analysis of volatiles from needles of five-needle pines of northern and eastern Eurasia
Authors:D V Domrachev  E V Karpova  S N Goroshkevich  A V Tkachev
Institution:1. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent??eva 9, Novosibirsk, 630090, Russia
2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia
3. Institute of Monitoring of Climatic and Ecological Systems, Siberian Branch, Russian Academy of Sciences, pr. Akademicheskii 10/3, Tomsk, 634055, Russian Federation
Abstract:The chemical composition of essential oil samples from needles of six species of five-needle pines (Pinus pumila, Pinus sibirica, Pinus parviflora, Pinus armandii, Pinus koraiensis, and Pinus cembra) and one natural interspecific hybrid Pinus sibirica × Pinus pumila has been studied by the chromato-mass spectrometry method. Essential oils have been prepared by simultaneous steam distillation-extraction. The analysis of the samples?? composition showed that the main constituents of the essential oils were the following mono- and sesquiterpenic compounds: ??-pinene (5?C63%), camphene (0.7?C3.6%), ??-pinene (0.7?C7%), ??-myrcene (0.5?C3.4%), 3-carene (0?C16%), limonene (0.6?C7.9%), ??-phellandrene (0.7?C5.3%), terpinolene (0.4?C6.7%), bornyl acetate (0.2?C12%), ??-terpenyl acetate (0?C4.6%), caryophyllene (0.4?C24%), humulene (0.1?C4%), germacrene D (0.1?C24%), bicyclogermacrene (0.1?C3.6%), ??-cadinene (0.9?C2.3%), ??-cadinene (2.2?C6.1%), germacrene D-4-ol (0?C6.8%), T-cadinol (0.7?C2.9%), and ??-cadinol (0.7?C6.0%).
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