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New Synthetic Tools for Peptide-Tetraphenylporphyrin Derivatives |
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| Authors: | De Luca Stefania Bruno Giovanni Fattorusso Roberto Isernia Carla Pedone Carlo Morelli Giancarlo |
| Affiliation: | (1) Centro Interuniversitario di Ricerca sui Peptidi Bioattivi & Centro di Studio di Biocristallografia, CNR, Via Mezzocannone 4, 1-80134 Napoli, Italy;(2) Dipartimento di Scienze Ambientali, Seconda Università di Napoli, Via Arena 22, I-81100 Caserta, Italy |
| Abstract: | Summary New metal-tetraphenylporphyrins and Fmoc-lysine-metalloporphyrin derivatives have been used to prepare peptide-porphyrin and peptide-metalloporphyrin compounds via solid-phase peptide synthesis. A water-soluble peptide, covalently bound to a manganese(III)-porphyrin, has been used as a catalyst to promote the oxidation of ABTS by hydrogen peroxide ort-butylhydroperoxide. |
| Keywords: | metalloenzymes peptide-porphyrins solid-phase peptide-synthesis |
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