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Synthesis of 2-deoxy-D-arabino/lyxo-hexopyranosyl disaccharides
Authors:Paul Somak  Jayaraman Narayanaswamy
Affiliation:Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India.
Abstract:Synthesis of 2-deoxy-D-arabino/lyxo-hexopyranosyl disaccharides is reported. In these, the disaccharides contain 2-deoxy-arabino-hexopyranosyl and 2-deoxy-lyxo-hexopyranosyl sugars as either the reducing or the non-reducing or both the sugar units of the disaccharides. The activated 2-deoxy-1-thioglycosides served as the common precursors to prepare the 2-deoxy disaccharides with the above configurations.
Keywords:Deoxysugars   Glycals   Glycosylations   Thioglycosides
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