Influence of Tl+ activator ions on the luminescence characteristics of KCl0.5Br0.5:Eu2+ powder phosphors |
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Authors: | S. Nagarajan R. Sudarkodi |
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Affiliation: | Department of Physics, Pondicherry Engineering College, Puducherry‐605014, India. |
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Abstract: | Photoluminescence (PL) of thallium co‐doped with KCl0.5Br0.5:Eu2+ powder phosphors display emission bands at 320 and 370 nm attributable to centres involving Tl+ ions in addition to characteristic Eu2+ emission around 420 nm. Additional PL excitation and emission bandS observed around 260 and 380 nm, respectively, were observed in the double‐doped KCl0.5Br0.5:Eu2+, Tl+ powder phosphors and are attributed to complex centres involving Tl+ and Eu2+ ions. The enhancement observed in the intensity of Eu2+ emission around 420 nm with the addition of TlBr in KCl0.5Br0.5:Eu2+ powder phosphors is attributed to the energy transfer from Tl+ → Eu2+ ions. Photostimulated luminescence (PSL) studies of γ‐irradiated KCl0.5Br0.5:Eu2+, Tl+ mixed phosphors are reported and a tentative PSL mechanism in the phosphors has been suggested. Copyright © 2009 John Wiley & Sons, Ltd. |
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