The role of oxygen substituents in the elimination and enolisation reactions of 4,6-O-benzylidene-hexopyranosides and -hexopyranosiduloses |
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| Authors: | Vernon G.S. Box |
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| Affiliation: | Department of Chemistry, University of the West Indies, Kingston 7 Jamaica, West Indies |
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| Abstract: | An attempt is made to rationalise the elimination and enolisation processes observed in 4,6-O-benzylidenehexopyranosides and hexopyranosiduloses. The roles of the oxygen substituents on the pyran ring are outlined, and it is suggested that these oxygen atoms control the paths of the reactions. |
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