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Photochemical cycloaddition of 1,3-diacetoxy-2-propanone to (trimethylsilyloxy)ethylene
Authors:Younosuke Araki  Jun-ichi Nagasawa  Yoshiharu Ishido
Institution:Department of Chemistry, Faculty of Science, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152 Japan
Abstract:The structures of two capsular polysaccharides elaborated by Haemophilus influenzae type e, strains NCTC 8455 and 8472, respectively, have been investigated, methylation analysis and n.m.r. spectrometry being the principal methods used. It is concluded that the polysaccharides are composed of repeating-units having the following structure:
/></figure> In the polysaccharide from strain NCTC 8472, all of the repeating-units contain the β-dfructofuranosyl group. The polysaccharide from strain NCTC 8455, however, contains only traces of d-fructose, corresponding to approximately one group per 100 repeating-units.</td>
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