Isolation of D-4-chlorotryptophane derivatives as auxin-related metabolites from immature seeds of Pisum sativum |
| |
Authors: | Shingo Marumo Hiroyuki Hattori |
| |
Institution: | (1) Department of Agricultural Chemistry, Nagoya University, Nagoya, Japan |
| |
Abstract: | Summary Three active compounds which induce hypocotyl swelling in Phaseolus mungo were isolated from immature seeds of Pisum sativum. For purification of the compounds, our three-step procedure (counter-current distribution, Sephadex LH 20, and partition chromatography on silicic acid) were used. The chemical structures of two of the compounds were determined by synthesis to be -N-carboethoxyacetyl- and -N-carbomethoxyacetyl-D-4-chlorotryptophane. D-4-Chlorotryptophane is the first naturally occurring chlorinated amino acid found. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|