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Water content of chlorophyll hydrate
Authors:Herbert Blaha  Peter Kis  Helmuth Springer-Lederer
Affiliation:1. Institute of Inorganic Chemistry, University of Vienna, Vienna, Austria.;2. Institute of Physical Chemistry, University of Vienna, Vienna, Austria.
Abstract:Thermogravimetry shows that polycrystalline chlorophyll a is a chlorophyll dihydrate. Neither thermogravimetry nor differential thermal analysis indicates the existence of a stable chl a monohydrate. Moreover it is found that larger amounts of water-free chlorophyll a (>50 mg) cannot be prepared by application of vacuum and heat in a reasonable time, if chemical decomposition is to be avoided. Thin layers of polycrystalline chlorophyll a undergo spectroscopic changes depending on temperature and vacuum.
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