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Heliangolides,and nerolidol and p-hydroxyacetophenone derivatives from Calea species
Authors:Ferdinand Bohlmann  Christa Zdero  Robert M King  Harold Robinson
Institution:1. Institute for Organic Chemistry, Technical University of Berlin, Strasse des 17. Juni 135, D-1000 Berlin 12, West Germany;2. Smithsonian Institution, Washington, DC 20560, U.S.A.
Abstract:A new Calea species afforded a heliangolide, closely related to niveusin C, while from Calea teucrifolia two new nerolidol derivatives and eight p-hydroxyacetophenone derivatives were isolated. The structures were elucidated by spectroscopic methods and a few chemical transformations. The spectral data of 8β-angeloylatripliciolide, the main constituent of C. teucrifolia, are also included. The chemotaxonomic situation is discussed briefly.
Keywords:Calea new sp    Compositae  sesquiterpene lactone  nerolidol derivatives  
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