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Trixikingolides and germacrene derivatives from Trixis species
Authors:Ferdinand Bohlmann  Antoinette Suwita  Jasmin Jakupovic  Robert M. King  Harold Robinson
Affiliation:1. Smithsonian Institution, Washington, DC 20560, U.S.A.
Abstract:The investigation of two further Trixis species afforded five new sesquiterpenes related to trixikingolide, six new germacrene derivatives and a sesquiterpene derived from rotundene. Some further known compounds were isolated too, which in part may be of chemotaxonomic significance. The structures were elucidated by spectroscopic methods and a few chemical transformations. The relative position of the ester groups in eight of the new sesquiterpenoids however, could not be established with certainty as partial saponifications were not successful.
Keywords:Compositae  Mutisieae  sesquiterpenes  trixikingolides  germacrene derivatives  rotundene derivative  flavanones.
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