Contributions to quantum biology. I. Mobile electronic characteristics of riboflavin radicals |
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Authors: | George Karreman |
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Institution: | (1) Department of Basic Research, Eastern Pennsylvania Psychiatric Institute, Philadelphia, Pennsylvania |
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Abstract: | Quantum biology is the quantum mechanical study of electrons in molecules of biological interest. This requires the solution
of problems involving many electrons. Approximation methods are therefore necessary and are discussed. The present study,
concerned with the mobile electrons in riboflavin (FMN) and its radicals (FMN−, FMNH and FMNH2
+), is based on the approximation method, developed by B. Pullman and A. Pullman. The solution of the eigenvalue problems so
obtained gives the energy levels of the mobile electron systems involved. The corresponding eigenvectors yield the mobile
electronic charges of the atoms of riboflavin radicals which have contributed mobile electrons. Important differences of the
net charge distributions of these radicals are emphasized. The longest wave length of light absorption is calculated from
the obtained energy levels and agrees, within the accuracy of the method, with corresponding experimental results. From the
appropriate calculated results, electronic assignments are obtained for the experimental transitions involved. |
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Keywords: | |
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