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Cyclic voltammetry characterization of metal complex imprinted polymer
Authors:Zeng Yi Ning  Zheng Ning  Osborne Peter G  Li Yuan Zong  Chang Wen Bao  Wen Mei Juan
Institution:The Key Laboratory of Bioorganic Chemistry and Molecular Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People's Republic of China.
Abstract:Polymer capable of specific binding to Cu(2+)-2, 2'-dipyridyl complex was prepared by molecular imprinting technology. The binding specificity of the polymer to the template (Cu(2+)-2, 2'-dipyridyl complex) was investigated by cyclic voltammetric scanning using the carbon paste electrode modified by polymer particles in phosphate buffer solution. Factors that influence rebinding of the imprinted polymer were explored. The results demonstrated that cyclic voltammetry was an efficient approach to explore interactions between template and imprinted polymers.
Keywords:Molecular imprinted polymer  Cu2+‐2  2′‐dipyridyl complex  carbon paste electrode  cyclic voltammetry
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