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Recent contributions of electronic circular dichroism to the investigation of oligopeptide conformations
Authors:Formaggio Fernando  Peggion Cristina  Crisma Marco  Kaptein Bernard  Broxterman Quirinus B  Mazaleyrat Jean-Paul  Wakselman Michel  Toniolo Claudio
Affiliation:Institute of Biomolecular Chemistry, CNR, Department of Chemistry, University of Padova, Padova, Italy. fernando.formaggio@unipd.it
Abstract:Recent applications in our laboratories of electronic circular dichroism to the study of peptide secondary structures and their changes under external stimuli are briefly reviewed. More specifically, this article deals with: 1). characterization of a novel peptide conformation; 2). origin of amino acid homo-chirality on Earth; 3). bend and helical peptides as spacers; and 4). transfer and propagation of chirality in peptides.
Keywords:circular dichroism  α‐helix  310‐helix  peptides  transfer of chirality  β‐turn
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