Stereoinversion of optically active 3-pentyn-2-ol by Nocardia species |
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| Authors: | Jun Ogawa Sheng-Xue Xie Sakayu Shimizu |
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| Institution: | (1) Division of Applied Life Sciences, Graduate School of Agriculture, Kyoto University, Sakyo-ku, Kyoto, 606-8502, Japan |
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| Abstract: | Nocardia fusca and Nocardia pseudosporangifera produced (R)-3-pentyn-2-ol and (S)-3-pentyn-2-ol in 24 and 72 h reaction, respectively, from (RS)-3-pentyn-2-ol, with greater than 70% molar yields through a stereoinversion reaction involving stereoselective oxidation and reduction with 3-pentyn-2-one as an intermediate. |
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| Keywords: | Nocardia pentyn-2-ol stereoinversion |
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