Total synthesis and identification of two diastereoisomers of 1-methyl-2-[N-(p-tolylsulfonyl)-2-pyrrolidinyl]ethyl beta-L-fucopyranoside |
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| Authors: | E Silva Maria Joselice Cottier Louis Srivastava Rajendra M Sinou Denis Thozet Alain |
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| Institution: | Departamento de Química Fundamental, Universidade Federal de Pernambuco, Cidade Universitária, 50.740-540 Recife, PE, Brazil. |
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| Abstract: | The reaction of a racemic mixture of (2R,2'S)- and (2S,2'R)-N-(p-tolylsulfonyl)-2-pyrrolidinyl-2-propanol, prepared from (S)-proline, with 2,3,4-tri-O-acetyl-alpha-L-fucopyranosyl trichloroacetimidate led to both diastereoisomers of the title compound after O-deacetylation. |
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| Keywords: | l-Proline" target="_blank">l-Proline β-Aminoalcohols l-Fucopyranosides" target="_blank">β-l-Fucopyranosides |
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