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A pentacyclic quinone diosindigo B from the heartwood of Diospyros melanoxylon
Authors:Akella VB Sankaram  Vaddu V Narayana Reddy  Gurbachan S Sidhu
Institution:Regional Research Laboratory, Hyderabad 500 009, India
Abstract:Diosindigo A, diosindigo B and biramentacéone have been isolated from heartwood of Diospyros melanoxylon. A violet pigment isolated from the same source has been shown to be a new pentacyclic quinone. Sunlight causes diosindigo B to change to the pentacyclic quinone and biramentacéone. The intense peaks at m/e 389 and 388 in the mass spectrum of diosindigo B are doublets which arise by fragmentation of both M+ and M+ + 2.
Keywords:Ebenaceae  naphthaquinones  diosindigo B  rearrangement  diosindigo A  biramentacéone  
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