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Assay of fluoride by a novel organic–inorganic mesoporous nano‐sized sensor
Authors:Qianmin Ma  Yuming Lai  Jinwei Gao  Qianming Wang
Institution:1. School of Chemistry and Environment, South China Normal University, Guangzhou, People's Republic of China;2. Institute for Advanced Materials, Academy of Advanced Optoelectronics, South China Normal University, Guangzhou, People's Republic of China;3. Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou, People's Republic of China;4. Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, Guangzhou, People's Republic of China
Abstract:In this report, we prepared a novel mesoporous silica nanostructure for selective detection of fluoride through ultraviolet absorption and emission changes. In the sensing system, a silica coupling reagent (3‐(triethoxysilyl)propyl isocyanate) linked 1‐naphthylamine has been covalently grafted onto the mesopores of inorganic network. These specially designed nanospheres can recognize fluoride from other anions based on hydrogen bond interactions. This approach may provide new opportunities for designing related sensing systems with enhanced physical or chemical properties. Copyright © 2016 John Wiley & Sons, Ltd.
Keywords:mesoporous  absorption  emission  nanoparticles
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