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Three‐Dimensional Nanostructured Indium‐Tin‐Oxide Electrodes for Enhanced Performance of Bulk Heterojunction Organic Solar Cells
Authors:Hyunah Kwon  Juyoung Ham  Dong Yeong Kim  Seung Jae Oh  Subin Lee  Sang Ho Oh  E Fred Schubert  Kyung‐Geun Lim  Tae‐Woo Lee  Sungjun Kim  Jong‐Lam Lee  Jong Kyu Kim
Affiliation:1. Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang, South Korea;2. Department for Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, NY, USA
Abstract:A three‐dimensional indium tin oxide (ITO) nanohelix (NH) array is presented as a multifunctional electrode for bulk heterojunction organic solar cells for simultaneously improving light absorption and charge transport from the active region to the anode. It is shown that the ITO NH array, which is easily fabricated using an oblique‐angle‐deposition technique, acts as an effective antireflection coating as well as a light‐scattering layer, resulting in much enhanced light harvesting. Furthermore, the larger interfacial area between the electrode and the active layer, together with the enhanced carrier mobility through highly conductive ITO NH facilitate transport and collection of charge carriers. The optical and electrical improvements enabled by the ITO NH electrode result in a 10% increase in short‐circuit current density and power‐conversion efficiency of the solar cells.
Keywords:nanohelix arrays  bulk heterojunction solar cells  organic solar cells
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