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High Performance Na0.5[Ni0.23Fe0.13Mn0.63]O2 Cathode for Sodium‐Ion Batteries
Authors:Ivana Hasa  Daniel Buchholz  Stefano Passerini  Bruno Scrosati  Jusef Hassoun
Institution:1. Department of Chemistry, University of Rome, Sapienza, Rome, Italy;2. Institute of Physical Chemistry, University of Muenster, Muenster, Germany;3. Helmholtz Institute Ulm, Karlsruhe Institute of Technology, Ulm, Germany;4. Italian Institute of Technology, Genova, Italy
Abstract:The synthesis of a new layered cathode material, Na0.5Ni0.23Fe0.13Mn0.63]O2, and its characterization in terms of crystalline structure and electrochemical performance in a sodium cell is reported. X‐ray diffraction studies and high resolution scanning electron microscopy images reveal a well‐defined P2‐type layered structure, while the electrochemical tests demonstrate excellent characteristics in terms of high capacity and cycle life. This performance, the low cost, and the environmental compatibility of its component poses Na0.5Ni0.23Fe0.13Mn0.63]O2 to be among the most promising materials for the next generation of sodium‐ion batteries.
Keywords:P2‐type materials  layered materials  cathodes  sodium‐ion batteries
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