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Structure and biosynthesis of lecanopyrone, a naphtho[1,8-cd]pyran-3-one derivative from cultured lichen mycobionts of Lecanora leprosa
Authors:Takenaka Yukiko  Hamada Nobuo  Tanahashi Takao
Institution:Kobe Pharmaceutical University, 4-19-1, Motoyamakita-machi, Higashinada-ku, Kobe 658-8558, Japan.
Abstract:From the cultures of spore-derived mycobionts of the lichen Lecanora leprosa a novel naphtho1,8-cd]pyran-3-one derivative, lecanopyrone, was isolated. Its structure was determined by spectroscopic methods. The assembly pattern of acetate units in its biosynthesis was verified using sodium 1-13C]-acetate and sodium 1,2-13C2]-acetate.
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