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Hydrogels obtained from an original catanionic system for efficient formulation of boron wood-preservatives
Institution:1. Laboratoire d''Etude et de Recherche sur le Matériau Bois (LERMAB), Faculté des Sciences et Technologies, Université de Lorraine, Boulevard des Aiguillettes, BP 70239, 54506 Vandoeuvre-lès-Nancy cedex, France;3. SRSMC – UMR 7565, Université de Lorraine, BP 70239, 54506 Vandoeuvre-lès-Nancy cedex, France;1. Department of Biomedical Engineering, Louisiana Tech University, Ruston, LA 71272, USA;2. Department of Chemical Engineering, The University of Texas at Austin, Austin, TX 78712, USA;3. Department of Biomedical Engineering, The University of Texas at Austin, Austin, TX 78712, USA;4. Division of Pharmaceutics, The University of Texas at Austin, Austin, TX 78712, USA;5. Institute for Biomaterials, Drug Delivery and Regenerative Medicine, The University of Texas at Austin, Austin, TX 78712, USA;6. Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA;7. Department of Biomedical Engineering, 3120 Texas A&M University, College Station, TX 77843-3120, USA;1. Engineering Laboratory for Energy System Process Conversion & Emission Control Technology of Jiangsu Province, School of Energy & Mechanical Engineering, Nanjing Normal University, Nanjing 210042, China;2. Institute of Chemical Industry of Forest Products, China Academy of Forest, 210042, China;1. Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, PO Box 91, H-1521 Budapest, Hungary;2. ‘Lendület’ Supramolecular Chemistry Research Group, Institute of Organic Chemistry, Research Centre of Natural Sciences, Hungarian Academy of Sciences, PO Box 286, H-1519 Budapest, Hungary;1. Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, PO Box 91, H-1521 Budapest, Hungary;2. ‘Lendület’ Supramolecular Chemistry Research Group, Institute of Organic Chemistry, Research Centre of Natural Sciences, Hungarian Academy of Sciences, PO Box 286, H-1519 Budapest, Hungary
Abstract:A new catanionic system associating amphiphilic carnosine (βAlaHisC8) and lauric acid forms supramolecular hydrogel at a very low concentration. This gel was investigated and we checked the validity of the concept of hydrogel utilization to reduce boron leachability and to develop new wood protection treatments. Impregnation with 5% aqueous borax solution (w/w) and 0.3% gelator agent (w/w) fosters improvement in the resistance of Scots pine sapwood subjected to water leaching toward the brown-rot fungus Poria placenta, while samples treated with 5% aqueous borax solution were partially degraded by the fungus. These results clearly indicate the effectiveness of hydrogel to retain boron in wood.
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