The study of bimolecular reactions under non-pseudo-first order conditions |
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Authors: | Malatesta Francesco |
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Institution: | Department of Pure and Applied Biology, University of L'Aquila, Italy. malatest@univaq.it |
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Abstract: | In this work a new equation which describes the time evolution of bimolecular reactions is derived and tested by experiment. The equation is general and the results show that second-order reactions of any simple type may be accurately described by a quotient of exponential functions. The model and reagent concentration dependent observed rate constants show a complex non-linear behaviour when experimental conditions deviate from pseudo-first order nevertheless reducing to the well-known linear dependence when pseudo-first order conditions are met. |
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