|
|||||
|
|
Development of a 1H NMR structural-reporter-group concept for the primary structural characterisation of alpha-D-glucans |
|
| Authors: | van Leeuwen Sander S Leeflang Bas R Gerwig Gerrit J Kamerling Johannis P |
| Affiliation: | Bijvoet Center, Department of Bio-Organic Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands. |
| Abstract: | An NMR study of proton chemical shift patterns of known linear alpha-D-glucopyranose di- and trisaccharide structures was carried out. Chemical shift patterns for (alpha1-->2)-, (alpha1-->3)-, (alpha1-->4)- and (alpha1-->6)-linked D-glucose residues were analysed and compared to literature data. Using these data, a 1H NMR structural-reporter-group concept was formulated to function as a tool in the structural analysis of alpha-D-glucans. |
| Keywords: | Structural-reporter-group concept α- smallcaps" >d-Glucan 1H NMR spectroscopy Polysaccharide structural analysis |
| 本文献已被 ScienceDirect PubMed 等数据库收录！ | |