Further kinetics studies of intermediates formed by flash photolysis of Mo(CO)6 |
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| Authors: | Enrique Lozano Diz |
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| Affiliation: | Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara CA 93106-9510, USA |
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| Abstract: | Kinetics studies of the behavior of Mo(CO)5(CH) in the presence of radical initiators were conducted in cyclohexane (CH) solution by laser flash photolysis with time-resolved infrared detection. Activation parameters were determined for reactions of Mo(CO)5(CH) with toluene and with photochemical radical generator dibenzylketone (DBK) in the presence of excess CO. |
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| Keywords: | Molybdenum Carbonyl TRIR Kinetics Mechanism |
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