Synthesis of alternating metallocopolymers by chiral recognition |
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Authors: | Maria Torres‐Werl Benoît Heinrich Aline Maisse‐Franois Stphane Bellemin‐Laponnaz |
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Institution: | Maria Torres‐Werlé,Benoît Heinrich,Aline Maisse‐François,Stéphane Bellemin‐Laponnaz |
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Abstract: | We report the synthesis of chiral enantiopure polytopic bridging ligands, which may lead to the formation of metallosupramolecular polymers with zinc (II) as metal linker. We show that chiral C2‐symmetric bisoxazoline ligands are useful moieties to efficiently generate heterochiral complexes and thus polymeric entities. The corresponding metallopolymers were further characterized by powder X‐ray diffraction (PXRD) to obtain information on the level of crystallinity of our different metallopolymers. |
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Keywords: | chiral bisoxazoline metallopolymer polytopic ligand zinc |
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