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Polymer-bound 1-aryl-3-alkyltriazenes as modular ligands for catalysis. Part 1: synthesis and metal coordination
Authors:Bräse Stefan  Dahmen Stefan  Lauterwasser Frank  Leadbeater Nicholas E  Sharp Emma L
Affiliation:1. Kekulé-Institut für Organische Chemie und Biochemie der Rheinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Strasse. 1, D-53121 Bonn, Germany;2. Institut für Organische Chemie, der Rheinisch-Westfälischen Technischen Hochschule Aachen, Professor-Pirlet-Strasse 1, D-52074 Aachen, Germany;3. Department of Chemistry, King''s College London, Strand, London WC2R 2LS, UK;1. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskoy Str, 22, Ekaterinburg 620990, Russia;2. Ural Federal University, Mira St. 19, Ekaterinburg 620002, Russia;3. Ural Research Institute for Dermatology, Venereology and Immunopathology, Scherbakova St., 8, Ekaterinburg 620076, Russia;4. Ural Research Institute for Phthisiopulmonology, 22 Parts’ezda St, 50, Ekaterinburg 620039, Russia;1. Department of Chemistry, University of Durham, Science Laboratories, Lower Mountjoy, South Road, Durham, DH1 3LE, UK;2. Department of Chemistry, College of Education for Pure Sciences, Mosul University, Iraq;1. United Graduate School of Agricultural Science, Tokyo University of Agriculture and Technology, 3-5-8 Saiwai-cho, Fuchu, Tokyo 183-8509, Japan;2. College of Agriculture, Ibaraki University, 3-21-1 Chuo, Ami, Inashiki, Ibaraki 300-0393, Japan;1. Institute of Chemistry, Saint Petersburg State University, Universitetskaya nab. 7/9, Saint Petersburg, 199034, Russian Federation;2. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bolshoii Pr. 31, Saint Petersburg, 199004, Russian Federation;3. South Ural State University, Lenin Av. 76, Chelyabinsk, 454080, Russian Federation;1. Institute of Environmental Science, and School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan 030006, China;2. Biology Institute of Shanxi, 50 Shifan Street, Taiyuan 030006, China;3. Partner State Key Laboratory of Environmental and Biological Analysis, and Department of Chemistry, Hong Kong Baptist University, 224 Waterloo Road, Kowloon Tong, Hong Kong SAR, China
Abstract:A range of di- and tri-substituted triazenes have been synthesized from a polymer-supported diazonium salt and various primary and secondary amines. The triazenes obtained were treated with transition metal salts to form polymer-supported metal complexes in firstly a general screen and then in a specific manner.
Keywords:
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