Research Program in Biogeochemistry, Departments of Biology, Chemistry, Geology, Indiana University, Bloomington, IN 47405, U.S.A.;Photosynthetic Bacteria Group, Department of Biology, Indiana University, Bloomington, IN 47405, U.S.A.
Abstract:
Abstract Small inverse isotope effects of 1–3‰ were consistently observed for the oxidation of sulfide to elemental sulfur during anaerobic photometabolism by Chromatium vinosum . The inverse fractionation can be accounted for by an equilibrium isotope effect between H2S and HS−, and may indicate that C. vinosum (and other photosynthetic bacteria) utilizes H2S rather than HS− as the substrate during sulfide oxidation.