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Radicals on surfaces formed by ionizing radiation
Authors:Masaru Shiotani  Mikael Lindgren
Institution:(1) Department of Applied Chemistry, Hiroshima University, 724 Higashi-Hiroshima, Japan;(2) Department of Physics and Measurement Technology, Chemical Physics, University of Linköping, S-581 83 Linköping, Sweden
Abstract:An overview is presented of radicals generated on porous metal oxide surfaces such as zeolites whose main source of generation has been ionizing radiation. Attention is primarily paid to ESR studies on structures and reactions of organic neutral and ionic radicals. A short introduction is also given to paramagnetic metal ions and clusters formed in zeolites and other related materials.
Keywords:ESR  radical  radical ions  ionizing radiation  paramagnetic metal ions  metal clusters  metal metal oxides  zeolites  alkane  alkenes  alkynes  benzene  fluorinated benzenes  sodium clusters  silver clusters  silica clathrates
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