Labdane diterpenes from Marrubium thessalum |
| |
Authors: | Catherine Argyropoulou Helen Skaltsa |
| |
Institution: | a Department of Pharmacognosy and Chemistry of Natural Products, School of Pharmacy, Panepistimiopolis, Zografou, GR-15771 Athens, Greece b Department of Pharmaceutical Sciences, University of Florence, Ugo Schiff 6, Polo Scientifico, Sesto Fiorentino, 50019 Florence, Italy |
| |
Abstract: | From the aerial parts of Marrubium thessalum, four labdane diterpenes, 13S-preperegrinine, 3α-hydroxymarrubiin, 9α,13R-15,16-bisepoxy-15β-methoxy-3-oxo-labdan-6β,19-olide and 15-methoxyvelutine C, have been isolated together with four known diterpenes and one methoxylated flavone, ladanein. The structures of the isolated compounds were established by means of NMR (COSY, HSQC, HMBC, NOESY, and ROESY) and MS spectral analyses. Complete NMR assignments are reported for 13R-preperegrinine. Characteristic compounds of the plant were peregrinine and ladanein. |
| |
Keywords: | Marrubium thessalum Lamiaceae Labdane diterpenes 2D NMR Marrubiin Ladanein |
本文献已被 ScienceDirect 等数据库收录! |
|