RDX (Hexahydro-1,3,5-trinitro-1,3,5-triazine) Biodegradation in Aquifer Sediments under Manganese-Reducing Conditions |
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Authors: | Paul M. Bradley Richard S. Dinicola |
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Affiliation: | a U.S. Geological Survey, 720 Gracern Road, Suite 129, Columbia, South Carolina, USAb U.S. Geological Survey, 1201 Pacific Avenue, Suite 600, Tacoma, Washington, USA |
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Abstract: | A shallow, RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine)-contaminated aquifer at Naval Submarine Base Bangor has been characterized as predominantly manganese-reducing, anoxic with local pockets of oxic conditions. The potential contribution of microbial RDX degradation to localized decreases observed in aquifer RDX concentrations was assessed in sediment microcosms amended with [U-14C] RDX. Greater than 85% mineralization of 14C-RDX to 14CO2 was observed in aquifer sediment microcosms under native, manganese-reducing, anoxic conditions. Significant increases in the mineralization of 14C-RDX to 14CO2 were observed in anoxic microcosms under NO3-amended or Mn(IV)-amended conditions. No evidence of 14C-RDX biodegradation was observed under oxic conditions. These results indicate that microbial degradation of RDX may contribute to natural attenuation of RDX in manganese-reducing aquifer systems. |
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Keywords: | anoxic aquifer biodegradation metal reduction microbial degradation RDX (hexahydro-1 3 5-trinitro-1 3 5-triazine) sediment microcosms |
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