The structure of d-threo-2,5-hexodiulosonic acid and derivatives in solution |
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| Authors: | Glenn C Andrews Bradley E Bacon Jon Bordner Glen LA Hennessee |
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| Institution: | Central Research, Pfizer Inc., Groton, CT 06340 U.S.A.;North Carolina State University, Raleigh, NC 27607 U.S.A. |
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| Abstract: | The structure of d-threo-2,5-hexodiulosonic acid (1) and various derivatives in solution was determined by 13C-n.m.r. spectroscopy to be a hydrated, pyranose form. The structures of the methyl ester of 1 and of its 5-(dimethyl acetal) were confirmed by chemical means and by X-ray structure analysis. |
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| Keywords: | To whom enquiries should be addressed |
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