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A simple enzymatic procedure for the synthesis of a hydroxylated polyester from glycerol and adipic acid |
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| Authors: | Luis E. Iglesias Yuko Fukuyama Hiroshi Nonami Rosa Erra-Balsells Alicia Baldessari |
| Affiliation: | (1) Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, 3°, Ciudad Universitaria, 1428 Buenos Aires, Argentina;(2) Plant Biophysics/Biochemistry Research Laboratory, College of Agriculture, Ehime University, 3-5-7 Tarumi, Matsuyama, 790-8566, Japan |
| Abstract: | Lipase B from Candida antarctica catalyzed regioselectively the polyesterification of glycerol and adipic acid. UV-MALDI-TOF-MS analysis of the polymers shows low molecular weight polyesters (1314-1716) with very narrow polydispersities (1.0–1.2). |
| Keywords: | enzymatic polymerization lipase regioselectivity UV-MALDI-TOF-MS |
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