Combined in-beam electron impact-B/E-linked scan mass spectrometry of oxazoline derivatives for the structure determination of long-chain unsaturated fatty acids |
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Authors: | Y M Yang J Y Zhang Z H Huang |
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Affiliation: | Laboratory of Mass Spectrometry, Shanghai Institute of Materia Medica, Chinese Academy of Sciences. |
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Abstract: | Long-chain unsaturated fatty acids (UFA) having up to six double bonds are derivatized to 2-substituted 4,4-dimethyloxazolines (DMOX) and then analyzed by combined in-beam electron impact (IBEI)-B/E-linked scan mass spectrometry. This technique provides highly characteristic mass spectra and may serve as an auxiliary means for direct structure determination of individual UFA in mixtures. |
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