Glycosylation in room temperature ionic liquid using unprotected and unactivated donors |
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| Authors: | Park Tae-Joon Weïwer Michel Yuan Xuejun Baytas Sultan N Munoz Eva M Murugesan Saravanababu Linhardt Robert J |
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| Institution: | Department of Chemical and Biological Engineering, Biotechnology 4005, Rensselaer Polytechnic Institute, 110, 8th Street, Troy, NY 12180, USA. |
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| Abstract: | Glycosylation in room temperature ionic liquid is demonstrated using unprotected and unactivated donors. Modest yields of simple benzyl glycosides and disaccharides of glucose, mannose and N-acetylgalactosamine were obtained in 1-ethyl-3-methylimidazolium benzoate with Amberlite IR-120 (H(+)) resin or p-toluenesulfonic acid as promoters. |
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