Photoproducts from DNA pyrimidine bases and polycyclic aromatic hydrocarbons |
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Authors: | G Michael Blackburn R G Fenwick G Lockwood and G M Williams |
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Institution: | Department of Chemistry, The University, Sheffield S3 7HF, UK |
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Abstract: | The major photoproduct formed between benzoa]pyrene and thymine is identified as 1-(benzoa]pyren-6-yl)-thymine by means of spectroscopic analysis and isotopic syntheses. Irradiation of 1-methylcytosine hydrochloride and anthracene gives two isolable photoproducts of which one is assigned the structure 5-(anthracen-9-yl)-1-methylcytosine. |
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