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Determination of reaction rate constants in the mammillary system
Authors:H. E. Hart  U. Malik  D. Sugerman
Affiliation:1. Department of Physics, City College of the City University of New York, 10031, New York, N.Y.
Abstract:It is shown that the individual rate constants can be determined for the composite chemical system: $$A + B_i rightleftarrows C_i ; i = 1...N$$ with only measurements of the unbound species,A(t), required. The dissociation rate constants can be determined by direct analysis of a single steady state tracer study. The association constants then follow from the analysis of stable equilibrium determinations reported earlier (Hart, 1965). An approximate solution when tracer methods are in-applicable is also given.
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