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Saccharide induced racemization of amino acids in the course of the Maillard reaction
Authors:H. Brückner  J. Justus  J. Kirschbaum
Affiliation:(1) Interdisciplinary Research Center, Institute of Nutritional Science, Department of Food Sciences, University of Giessen, Federal Republic of Germany, DE
Abstract:Summary. The formation of D-amino acids on heating aqueous solutions of protein L-amino acids at pH 2.5 and pH 7.0 together with glucose, fructose or saccharose was investigated by enantioselective gas chromatography. The saccharide induced partial racemization (epimerisation) of L-amino acids is attributed to the Maillard reaction. Received October 1, 2001 Accepted October 2, 2001
Keywords:: D-amino acids  Maillard reaction  Nonenzymic browning  Racemization mechanism  Saccharides (glucose  fructose  saccharose)  Gas chromatography  Chirasil-L-Val
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