Conformational properties of N',N'-dimethylamides of N-acetyldehydroalanine and N-acetyl-(Z)-dehydrophenylalanine |
| |
| Authors: | Siodłak D Broda M A Rzeszotarska B Kozioł A E Dybała I |
| |
| Affiliation: | Institute of Chemistry, University of Opole, Poland. |
| |
| Abstract: | Conformational preferences of Ac-deltaAla-NMe2 and Ac-(Z)-deltaPhe-NMe2 were studied and compared with those of their monomethyl counterparts as well as with those of their saturated analogues. X-Ray data and energy calculations revealed a highly conservative conformation of the dehydro dimethylamides, which is located in a high-energy region of the Ramachandran map. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
