|
|||||
|
|
Investigation of the system cobalt(II) bovine carbonic anhydrase B-trichloroacetaldehyde. |
|
| Authors: | I Bertini E Borghi G Canti C Luchinat |
| Institution: | Universitä di Firenze and Laboratorio per lo Studio dei Composti Coordinazione del CNR, Florence, Italy |
| Abstract: | The interactions between hydrated trichloroacetaldehyde and cobalt(II)bovine carbonic anhydrase B have been investigated as a function of pH by means of electronic spectroscopy of FT nmr spectroscopy. The hydrated aldehyde is bound to the metal ion and its apparent affinity constant is pH dependent with a bell-shaped profile. The kinetic parameters of the dissociation process have also been determined. |
| Keywords: | Address reprint requests to: I Bertini Instituto di Chimica Generale e Inorganica Facolta di Farmacia Universitä di Firenze Via G Capponi 7 50121 Florence Italy |
| 本文献已被 ScienceDirect 等数据库收录！ | |