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Single-flask synthesis of (C5H5)W(CO)3Cl from W(CO)6
Authors:Norris W Hoffman
Institution:Union Carbide Corporation, P.O. Box 8361, South Charleston, W.V. 25303, U.S.A.
Abstract:(C5H5)W(CO)3Cl has been prepared in >90% yield from W(CO)6, cyclopentadiene, and CCl4 in a single-flask synthesis involving the intermediates W(CO)3(CH3CN)3 and (C5H5)W(CO)3H.
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