Synthesis and characterization of gold(III) complexes of 1,4-benzodiazepin-2-ones. Crystal structure of trichloro-[7-chloro-1-(cyclopropylmethyl)-1,3-dihydro-5-phenyl-2H-1,4-benzodiazepin-2-one]gold(III) |
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| Authors: | Giovanni Minghetti Maria Luisa Ganadu Candida Foddai Maria Agostina Cinellu Franco Cariati Francesco DeMartin Mario Manassero |
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| Institution: | Istituto di Chimica Analitica dell''Università, Via Vienna 2, 07100 Sassari, Italy;Dipartimento di Chimica Inorganica e Metallorganica dell''Università, CNR Center, 20133 Milan, Italy;Laboratorio di Strutturistica, Facoltà di Scienze, CNR Center, Università di Milano, Via Venezian 21, 20133 Milan, Italy |
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| Abstract: | The reaction of gold(III) chloride with several 1,4-benzodiazepin-2-ones, L, gives 1:1 adducts, (L)AuCl3*, which were characterized by IR, Raman and 1H NMR spectroscopy. In the title compound the coordination of the ligand, ascertained through a X-ray structure determination, was shown to occur through the 4-nitrogen atom. |
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| Keywords: | Author to whom correspondence should be addressed |
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