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Polarographic and spectrophotometric studies on the equilibration of Mo(V) species in HCl solutions
Authors:Sadayuki Himeno  Atsuyoshi Saito  Masatomo Hasegawa
Affiliation:Department of Chemistry, College of General Education, Kobe University, Nada-ku, Kobe 657, Japan
Abstract:The equilibration of Mo(V) species has been investigated in 0.5–5 M HCl (I = 5.0). The equilibria involve the dimer(D1)-dimer(D2) interconversion, followed by the decomposition of D2 to a monomeric form at greater acidities:
/></figure> The equilibrium constants have been determined as K<sub>1</sub> = 2 ± 0.3 and K<sub>2</sub> = (1.5 ± 0.4) X 10<sup>?8</sup> at 25 °C.</td>
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