Halogenated anthraquinones from the rare southern Illinois lichen Lasallia papulosa |
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Institution: | 1. P G Department of Studies in Biotechnology and Microbiology, Karnatak University, Dharwad 580003, Karnataka, India;2. Department of Microbiology and Biotechnology, Bangalore University, Jnana Bharathi Campus, Bangalore 560056, Karnataka, India |
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Abstract: | Abstract:Four anthraquinones were isolated from the foliose lichen, Lasallia papulosa (Ach.) Llano. Two of the anthraquinones are known compounds, previously isolated from Lasallia papulosa, while the other two were reported previously as secondary metabolites from laboratory-cultured Nephroma laevigatum, and are isolated here for the first time from lichens in their natural habitat. All compounds were characterized by UV spectrophotometry, mass spectrometry, 1H NMR and 13C NMR. The products were identified as 7-chloroemodin, valsarin (7-chloro-5-hydroxyemodin), 5-chloro-1- O -methylemodin and 5-chloro-1- O -methyl-ω-hydroxyemodin. |
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